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This song doesn't yet have a title, but in concert JoCo called it "Untitled Song About Marriage" and set lists from the show had it listed as both "40" and "Upon Turning 40." Photos of the two set lists can be viewed here and here on Flickr.
This song was performed in concert for the first time on March 25th, 2011 in Asheville, NC. That performance can be viewed on YouTube.
"Untitled Song About Marriage" is thus far not officially available in any medium.